Friday, August 25, 2023

ITALIAN ANTIMONY AND BORON BUT NO COINS IN A FOUNTAIN

 

One of the problems for an ole plugger like me is to purchase a very small collection, 10 or a dozen specimens, and then decide that a few of the minerals may be too complicated (especially too small) to describe on this Blog. Most of the time these minerals are not in my meager mineralogical vocabulary and are often from non-North/South American mines. It is then that I thank the existence of MinDat!

Two recent specimens are from mines in Italy, and I have spent several hours trying to learn something about the mines and their minerals. I suppose that is the meaning of being a lifelong learner!

The Le Cetine di Cotorniano Mine, Chiusdino, Siena Province, Tuscany, Italy, is a closed antimony mine that only lasted for a couple of years in the mid-1940s. I tried to locate something about the history of the mine but since I do not read Italian, I was in a bind. What was interesting, at least to me, was that the mine operated right at the end of WWII (1943-1945). Was the antimony used in the “war effort” and was the mine discarded with the capitulation of German and Italian fascists holding the northern part of the country? I don’t know.

Dark, elongated stibnite crystals (submillimeter in length), the major source of antimony at the Mine



Yellow to yellow tan tripuhyite. Top crystal cluster is submillimeter in length as is the lower massive (with a few crystals) aggregate.

What I do know is that this small, obscure mine, at least to me, has a modern inventory of 83 valid minerals including five Types. Four of these five Types have antimony in various oxidation states. The specimen I purchased is tripuhyite [FeSbO4], an antimonate (a metal; ferric iron 3+), oxygen (2-), and antimony with an oxidation state of 5+. Crystals are mostly composed of fibers that range from washed out yellow to brownish yellow to brown to brownish black. At times the fibers appear as a “mass of worms” while other specimens exhibit rosettes of fibers/crystals. The Clara Mine in Germany has produced some beautiful “blooming” rosettes and spherical crystal aggregates. The luster is usually dull to waxy, and someone has measured the hardness as ~6-7 (Mohs). 
The vug containing several minerals. Maximum width of vug ~3 mm. The yellow mystery mineral occupying most of the vug may be ?jarosite (see below).




My tripuhyite specimens occur within a vug from the mine matrix and are extremely small with individual crystals less than one mm. The mystery mineral that occupies most of the vug, well it is a mystery! The older label from Minerals Unlimited stated calcite; however, it is not a carbonate. My best guess is a few larger amber crystals are elpasolite [K2NaAlF6] while the majority of the smaller vitreous crystals are jarosite [KFe3+3(SO4)2(OH)6]. Due to the “smallness” of the crystals I cannot obtain good photos. I have identified a few stibnite crystals [orthorhombic Sb2S3] and a bright crimson dimorph of stibnite called metastibnite [amorphous Sb2S3].  There are tiny, numerous, scattered, acicular crystals that could be cetineite [(K,Na)6Sb3+12(Sb3+S3)2O18(OH)0.5 ·5H2O] but I would need an electronic gizmo to give me some ID help. There are also other unknown minerals in the small vug!


Are these amber crystals elpasolite? Again they are submillimeter in size.



Bright crimson metastibnite. It evidently forms from the oxidation of stibnite, its crystalline dimorph. I am uncertain about the hexagonal stack of crystals.

MinDat (retrieved 23 August 2023) stated “Mineralization in brecciated dolomitic limestones developed in Triassic evaporitic deposits which has been silicified by hydrothermal fluids circulating in the fault system. These fluids deposited the stibnite mineralization.”

My second Italian Mine is the Brosso Mine located within the city of Turin. The mines have been known since ancient times for the abundance and great variety of their minerals, of which samples exist in all the collections of Europe. The beginning of the cultivation of these mines dates back, according to the news reported in the "Monograph of the Sclopis brothers", to the time of the Romans, who apparently practiced lead and silver metallurgy starting from the argentiferous galena. [Translated from comunee.Brosso.to.it;  Miniere di Brosso.]

By the 18th Century miners were after pyrite to produce iron II sulfate [FeSO4-xH2O] that was used in the textile industry to fix various dyes and to blacken leather. By the late 1800s industry was distilling Brosso pyrite to produce sulfuric acid [H2SO4]. Although tough to find these days, Brosso collectors cherish specimens of pyrite crystals mixed with magnetite crystals.

As a small sidenote, starting about in the 5th Century ferrous sulfate was mixed with tannic acids (from plants) to produce writing, and later, printing inks.

After the pyrite mining was abandoned, and perhaps in the 1960s, the Brosso was “reopened” as a specimen mine for fine minerals that had formed between the zone where intrusive igneous monzonite and marbles had become interbedded in mica schists. Mineralization, especially of secondary boron minerals, occurred between szaibelyite and ludwigite where they came into contact with each other inside the magnetite skarns (Ferris and others, 1978 and Giussani and Vighi, 1964).

The Brosso has produced, according to MinDat, 108 different minerals including one type specimen (the boron mineral canavesite). The thumbnail specimen I have is composed of magnetite, a little pyrite, and szaibelyite, an anhydrous magnesium borate [MgBO2(OH)]. The latter is mostly found in boron-bearing skarn limestones and dolomitic marbles, or in evaporitic deposits where it is an alteration product of boron minerals like inyoite and colemanite; more rare in banded iron formations and serpentinites.





Black magnetite with white and buff fibers/lathes of szaibelyite. Width FOV ~7 mm.

Szaibelyite occurs as flatted fibers or lathes often as aggregates. Interestingly these fibers are inflexible and have a conchoidal fracture. They are white to buff in color, have a luster of dull to silky, and are soft (~3.5 Mohs). It is not the most handsome mineral in the cabinet but come from a quite historic and famous mine and ended up in the collection of Mineralogical Research Company before my purchase.

REFERENCES CITED

Ferraris, G., M. Franchini-Angela, 1978, Canavesite, A New Carboborate Mineral from Brosso, Italy: Canadian Mineralogist, Vol.16.

Giussani, A., L. Vighi, 1964: Caratteristiche e genesi dei minerali di boro, ludwigite, ferroludwigite, szaibelyite, camsdellite della miniera di Brosso (Ivrea). Periodico di Mineralogia, 33. Translated to: Characteristics and genesis of the ores of boron, ludwigite, ferroludwigite, szaibelyite, camsdellite of the Brosso mine (Ivrea). Mineralogy Periodical, 33.

AS for the coins in the Trevi Fountain:

The myth, originating in 1954 with the movie "Three Coins in the Fountain," goes like this:

  • If you throw one coin: you will return to Rome.
  • If you throw two coins: you will fall in love with an attractive Italian.
  • If you throw three coins: you will marry the person that you met.

In order to achieve the desired effect, you should throw the coin with your right hand over your left shoulder.

An interesting statistic is that approximately a million euros worth of coins are taken from the fountain each year. Since 2007 this money has been used to support good causes.

Tuesday, August 8, 2023

HINSDALITE & FLEECED AT THE GOLDEN FLEECE MINE

 


Golden Fleece Mine, Hinsdale County, Colorado. 2018 Photo by Jeffrey Beall, CC BY 4.0 <https://creativecommons.org/licenses/by/4.0>, via Wikimedia Commons.

Back country enthusiasts in Colorado are aware of Otto Mears and his road building (mostly toll roads) experiences in the high mountains in the southwestern part  of the state, especially in the San Juans. For example, he constructed the high mountain highway connecting Silverton to Ouray over Red Mountain Pass, and the Leadville Road over Poncha Pass. He also was into building several narrow-gauge railroads to access mining districts including the Rio Grande Southern Railway from Durango to Ridgeway over Lizard Head Pass. And last but not least, he was the mover and shaker in getting the dome of the Colorado Capitol gilded with 200 ounces of gold.

At any rate, a fellow road builder by the name of Enos Hotchkiss hooked up with Mears in ~1874 to construct a road from Saguache to Lake City. Along the way, near the current Lake San Cristobal, Hotchkiss noticed some interesting ore rocks and filed a claim, the Hotchkiss Claim. It turns out that Hotchkiss had a good eye for ore, and the Hotchkiss Mine was off and running. Unfortunately, in late 1876 poor ole Enos was badly injured as he fell several feet down a shaft. The Mine was idled for several months until new owners appeared and renamed the Hotchkiss to the Golden Fleece Mine. Gold, silver, and lead with minor copper and zinc were the major metals produced. The Mine also stimulated the economy in Lake City as numerous other mines went into production and a rail spur reached Lake City in 1889. The Lake City Mining District was booming. The Golden Fleece shipped one rail car containing ~$50,000 of high-grade ore while in 1895 the Black Crook Mine sent out ~$200,000 of pretty decent ore.  In early December the Golden Fleece was listed on the Colorado Springs Mining Exchange [Golden Fleece Mining and Milling Company (Iowa)] opening at $1.10 per share and closing at $1.30. The Company purchased the Colorado City Mine in Cripple Creek and also had an interest (owned?) producing gold mine(s) in Georgetown. But that was it, the boom was soon off, and the bust hit the entire Lake City Mining District. Evidently, “bad luck” prevented the miners from finding new veins. Although the mines in the Lake City District were exhausted all was not lost as the Golden Fleece had produced almost a million and a half dollars of gold (today’s price? )and silver before shutting down, and restarting, and shutting down, etc. In 1897 the shares were going for $.56, in 1900 $.26 and everything ended in 1903 at $.06. Well, sort of ended as businesses piddled around with the mine until about 1920.

The Golden Fleece was not helped by the fact that during the boom years a “systematic robbery by professional thieves” had siphoned off about half of the gold output. As best I can determine the “professionals” worked in the mines and simply high graded the ore and took it out in their “lunchboxes.” Then the Pinkerton National Detective Agency caught up with the bad guys. [Check out the newspaper articles in References Cited section].

MinDat (August, 2023) lists 46 valid minerals known from the Golden Fleece Mine including native gold and several gold bearing tellurides, various ore minerals: several silver bearing minerals, galena (lead), covellite (copper), bismuth (bismuthinite), sphalerite (zinc), etc. In addition, there are rare minerals such as mawsonite (copper-iron-tin sulfide) and melonite (nickel telluride. See previous post) and others. The Golden Fleece is the Type Locality for one mineral, hinsdalite, named after Hinsdale County, Colorado, home of the Golden Fleece.. The County is one of the most remote in the lower U.S. and a mecca for mountain climbers with five fourteeners and several thirteeners. Colorado 149 from Smith Fork north to Powderhorn through Creede and Lake City is one of the most majestic highways in the country.

Green hinsdalite from the Golden Fleece Mine. Width FOV ~3mm.
 

Hinsdalite [PbAl3(PO4)(SO4)(OH)6] is a hydroxy (OH) phosphate (PO4) – sulfate (SO4) and some mineralogists also stick in strontium as another cation with lead and aluminum as the mineral contains almost 4% of this element (see Webmineral.com). Hinsdalite contains two oxyanions, sulfate and phosphate, a rather unusual occurrence. Although some specimens show crude rhombohedral crystals or hexagonal plates my specimen from the dump at Golden Fleece is extremely small but does have a botryoidal green crust of hinsdalite. There are other tiny areas of porcelaneous green masses, but crystals seem to be absent. The botryoids have a greasy luster, seem to be translucent, and a measured hardness of ~4.5 (Mohs). Hinsdalite is a secondary mineral in the oxidized zones of polymetallic  (especially sulfides and tetrahedrite) ores. It is forms a solid solution series with, and is visually indistinguishable from, plumbogummite [PbAl3(PO4)(PO3OH)(OH)6]  except by electronic gizmos determining the phosphorous-sulfur ratio (Frost and others, 2011). MinDat does not list plumbogummite as being present at the Golden Fleece, hence the use of hinsdalite.

I have noted in other posts that the phosphate anion (PO4) and the arsenate anion (AsO4) are of similar size and chemical makeup and may substitute for each other. Hinsdalite with PO4  is the phosphate analogue of hidalgoite [PbAl3(AsO4)(SO4)(OH)6]. Van Wambeke (1971) believed that hinsdalite in a rock unit or erosional detritus  may indicate the presence of valuable ore minerals.         


 

 

Spherical encrustation of tan to orange hidalgoite composed of microcrystals; each sphere ranges from .3-.5 mm. Specimen is from Gold Hill, Utah.

 REFERENCES CITED

Frost, R.L., S.J. Palmer, and Yunfei Xi, 2011, A vibrational spectroscopic study of the mineral hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6: Journal of Molecular Structure, vol. 1001, Issues 1-3.

Van Wambeke, L., 1971, Hinsdalite and corkite: Indicator minerals in central Africa: Mineral Deposita vol. 6.

The Golden Fleece Robbery

 The New York Times, June 16, 1895, p. 1: Fortunes in Pilfered Mine Washings; Golden Fleece Company Loser - Thousands to Spend to Punish Thieves.

 San Francisco Call, June 15, 1895, p. 4: Robbery of a Rich Mine, Daring Theft of Ore at the Golden Fleece in Colorado.

 The New York Times, June 17, 1895, p. 1: Colorado's Mine Thieves. Probable They Have Stolen Ore Worth Millions Of Dollars. Have Been Operating Ten Years. No Doubt They Have an Organization and Careful Methods of Robbing — Many Mine Owners Suffer.

Siringo, Charles A.: A Cowboy Detective: A true story of twenty-two years with a world-famous detective agency, Chicago : W. B. Chonkey Co., 1912; published in several other reprinted editions.

 Sunday Herald (Syracuse, NY), June 23, 1895, p. 6: ROBBING A MINE. Systematic Fleecing of Ore of the Richest Gold Properties